Helium nanodroplet isolation spectroscopy in an undergraduate teaching laboratory

نویسندگان

چکیده

A home-built helium nanodroplet isolation spectrometer has been utilized by undergraduate students in course-based experiments to investigate the rovibrational dynamics of small molecules. Helium nanodroplets are a versatile medium that simplifies spectroscopy embedded molecules owing their low temperature (0.4 K) and weakly interacting nature. In infrared spectral region, this often results number rotationally resolved lines can be observed analyzed within several lab periods. We demonstrate advantages using well-established technique an upper-level chemistry course for which laser solvated 13C-labelled formic acid was investigated first time.

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ژورنال

عنوان ژورنال: Journal of Molecular Spectroscopy

سال: 2022

ISSN: ['0022-2852', '1096-083X']

DOI: https://doi.org/10.1016/j.jms.2022.111676